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Q.

Consider the following equilibria at 300 K

2A(g)+H2O(g)C(g)+3D(g)KP=3×1022atm

The equilibrium was attained in a container by taking A, C and D at partial pressures of 2 atm each along with large amount of liquid water. If vapour pressure of water at 300 K is 38 mm of Hg then calculate partial pressure of A when equilibrium gets established. [Express your answer in terms of 1010atm 

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answer is 5.

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Detailed Solution

When the compound A reacts with water molecule, then reaction takes place as,

2A(g)+H2O(g)C(g)+3D(g) 20.0522~00.0535

3×1022=3×535×102×PA2 PA=5×1010

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