Q.

Consider the following first order decomposition reaction A4(g)4A(g)
 Correct statements regarding the reaction . [log2=0.3]
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a

At 30 min, only  20% reaction  is complete

b

The time of intersection of two curves is independent of initial concentration of  A4

c

Rate of reaction   decreases linearly with time 

d

t1/2  of reaction  is 90 min

answer is A, B, D.

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Detailed Solution

   A4                                        4A
  t=0 am   0
t=30  (ax)m   4xm              
As                ax=4x     x=a/5
Percentage r×n  at  t=30  min
 =xa×100=20%
Now,  30=t1/2log2.logaaxt1/2=90  min

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Consider the following first order decomposition reaction A4(g)→4A(g) Correct statements regarding the reaction . [log2=0.3]