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Q.

Consider the following four electrodes 

P=Cu+20.0001M/Cus Q=Cu+20.1M/Cus R=Cu+20.01M/Cus S=Cu+20.001M/Cus

If the standard electrode potential of Cu+2/Cus  is 0.34V, the reduction potentials in volts of the above electrodes follows the order

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a

Q>R>S>P

b

P>Q>R>S

c

R>S>Q>P

d

P>S>R>Q

answer is A.

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Detailed Solution

Ered =Eredo-0.059nlog1Cu+2

Greater the concentraton of Cu+2  greater will be the reduction potential.

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