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Q.

Consider the following four halogen containing organic compounds:

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Choose the correct statement(s) among the following regarding the reactions of these compounds.

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a

II is more reactive than I towards methanol.

b

IV is more reactive than III towards PhSNa.

c

On heating with  EtONa/EtOH, II gives single alkene while IV gives three isomeric alkenes.

d

On nucleophilic substitution by  NaSH, IV gives an optically pure primary thiol as the major product.

answer is A, B, C, D.

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Detailed Solution

A) With Methanol both I and II undergo SN1 reaction and II is more reactive than I due to +R effect of OMe.
B) IV is more reactive than III towards PhSNa due to NGP by Ph group.
C) Question Image

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D) Major product is the abnormal product formed by NGP. 

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