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Q.

Consider the following ionisation enthalpies of two elements 'A' and 'B' 

Element Ionisation enthalpy kJmol
 1st  2nd3rd
A899 1757 14847
B737 1450 7731

 Which of the following statements is correct?

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a

Both 'A' and 'B' belong to group-1 where 'A' comes below 'B'

b

Both 'A' and 'B' belong to group-1 where 'B' comes below 'A'

c

Both 'A' and 'B' belong to group-2 where 'B' comes below 'A'

d

Both ' A ' and 'B' belong to group-2 where 'A' comes below 'B'

answer is C.

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Detailed Solution

Both 'A' and 'B' are members of group 2, where 'B' is placed below 'A'.

We notice that the second and third ionisation energies differ significantly. This is typical of metals made of alkaline earth. To create a dipositive ion with a stable electronic structure, they lose 2 valence electrons. It will take a lot of energy to remove the third electron because doing so will disrupt the stable arrangement of the noble gas.

The ionisation energy drops as one descends the group. The needed option is 3 since B's first ionisation energy is lower than A's, hence B comes after A.

Hence, the required option is C)  Both 'A' and 'B' belong to group-2 where 'B' comes below 'A'.

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Consider the following ionisation enthalpies of two elements 'A' and 'B' Element Ionisation enthalpy kJmol 1st  2nd3rdA899 1757 14847B737 1450 7731 Which of the following statements is correct?