Q.

Consider the following list of reagents :

Acidified K2Cr2O7, alkaline KMnO4,CuSO4,H2O2Cl2,O3,FeCl3,HNO3  and Na2S2O3 . The total number of reagents that can oxidise aqueous iodide to iodine is :

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answer is 7.

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Detailed Solution

6KI+K2Cr2O7+7H2SO44K2SO4+Cr2SO43

+3I2+7H2O

2CuSO4+4KICu2I2+2K2SO4+I2

H2O2+2KII2+2KOHCl2+2KI2KCl+I2O3+2KI+H2O2KOH+I2+O2

2FeCl3+2KI2FeCl2+2KCl+I24HNO3+2KI2KNO3+NO2+I2+2H2O

Na2S2O3 reacts with I2​ to form iodide

There are 7 such reactions in which oxidise aqueous iodide is converted into iodine and KMnO4​ cannot.

Thus, the correct answer is 7.

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