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Q.

Consider the following metallurgical processes :
(I) Heating impure metal with CO and distilling the,resulting volatile carbonyl (b.p. 43°C) and finally decomposition at 150°-200°C to get the pure metal
(II) Heating the sulphide ore in air until a part is converted to oxide and then further heating in the absence.of air, to let the oxide react with unchanged metal sulphide
(Ill)Electrolysis of the molten electrolyte containing approximately equal amounts of the metal chloride and NaCl to obtained the metal
The processes used for obtaining magnesium, nickel and copper are respectively :

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a

(I), (II) and (III)

b

(II), (III) and (I)

c

(III), (I) and (II)

d

(II), (I) and (III)

answer is C.

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Detailed Solution

 (I) Ni (impure)+4CO50CNiCO4(volatile) 230CNi (pure) +4CO
 (II)  Cu2S+32O2ΔCu2O+SO2
Cu2S+2Cu2O high  temp. 6Cu+SO2
 (III) MgCl2(s) electrolysis Mg2+(l)+2Cl(l)
 At cathode : Mg2++2eMg(s)
 At anode:  2Cl(l)Cl2(g)+2e

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