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Q.

Consider the following molecules and statements related to them:

A) 

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B) 

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a) (B) is more likely to be crystalline than (A)

b) (B) has higher boiling point than (A)

c) (B) dissolves more readily than (A) in water

 Identify the correct option from below:

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a

(a) and (c) are true

b

(b) and (c) are true

c

only (a) is true

d

(a), (c) and (b) are true

answer is D.

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Detailed Solution

(a) B is likely to be more crystalline as it may form parallel polymeric chains which helps it crystallize.

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will have higher boiling point due to effective intermolecular H – bonding

(C) (B) will be more soluble due to more H- bonding with water molecules H – bonding with water will be less in (A) due to intermolecular H – bonding

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