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Q.

Consider the following oxoacids of phosphorus : H3PO4H3PO3 and H3PO2 All ' P ' atoms in the oxoacids and oxoanions are 4 coordinate and contain at least one P=O unit. All ' P ' atoms in oxoacids have at least one P-OH group which ionises to give H+ion. The oxidation state of ' P ' is +5 only when it is directly attached to 4 oxygen atoms. For every two units decrease in oxidation state of Phosphorus, there is one P-H bond.

The number of H-atoms directly attached to 'P' in one molecule of each of H3PO4,H3PO3 and H3PO2are respectively

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a

0, 1 and 2

b

1, 0 and 2

c

2, 1 and 0

d

0, 2 and 1

answer is A.

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Detailed Solution

in  H3PO2 there is 2PH bonds 

in H3PO3 there is 1PH bonds 

in H3PO4 there is 0P-H bonds

The number of P−H bonds in H3PO2H3PO3 and H3PO4 is 2, 1, 0 respectively.

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Consider the following oxoacids of phosphorus : H3PO4, H3PO3 and H3PO2 All ' P ' atoms in the oxoacids and oxoanions are 4 coordinate and contain at least one P=O unit. All ' P ' atoms in oxoacids have at least one P-OH group which ionises to give H+ion. The oxidation state of ' P ' is +5 only when it is directly attached to 4 oxygen atoms. For every two units decrease in oxidation state of Phosphorus, there is one P-H bond.The number of H-atoms directly attached to 'P' in one molecule of each of H3PO4,H3PO3 and H3PO2are respectively