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Q.

Consider the following parallel, first order processes
AE1kiPAE2k2Q}k1,k2  are rate constants and  E1 and E2 are activation energies. 
The correct deduction(s) is (are)
 

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a

If a catalyst is added, it will decrease both  E1 and E2 but by same amount.

b

At any time, the ratio of concentration of P and Q has a fixed value at a given temperature.

c

If ‘E’ represents the overall activation energy for decay of A, it will be  (E1k1+E2k2k1+k2)

d

If ‘k’ represents the overall rate constant for decay of A, it will be  k1+k2

answer is A, C, D.

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Detailed Solution

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knet=k1+k2   AeEa/RT=A1eEa/RT+A2eEa2/RT 

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Ea=Ea1k1+Ea2k2k1+k2

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