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Q.

Consider the following process (each step involves a reversible change) 

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Considering the ideal gas behavior of  H2 gas, Select the correct choice(s): 

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a

ΔSXY=ΔSZY=95.7JK1

b

ΔSXZY=0

c

ΔSXY=95.7JK1

d

ΔSXZ=0

answer is A, C, D.

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Detailed Solution

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A)  ΔSXZ=qT=0 (reversible adiabatic change)
B)  ΔSXZY=ΔSXY=2.303×5×8.314log1010010=95.7  JK1
(because ‘S’ is a state function).
C) ΔSXY=95.7  JK1 (Reversible isothermal expansion)
D) Since ‘S’ is a state function, so  
 ΔSXY=ΔSXZ+ΔSZY=95.7  JK1 =0+ΔSzy=95.7
So, A,C and D correct

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