Q.

Consider the following processes

Process (1) C2H5OH/H,LiAlH4,PCC

Process (2),NaBH4,Cu/300C

Process (3) PCl5,LiAlH4,CrO3/H2SO4

Process (4) SOCl2,Pd/BaSO4/H2

The process by which acetic acid can be converted into acetaldehyde is/are

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a

1, 3, 4

b

2

c

1,2, 3,4

d

1,4

answer is B.

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Detailed Solution

Process (1) C2H5OH/H,LiAlH4,PCC

CH3COOC2H5+4HNa/C2H5OH or LiAlH42CH3CH2OH 

Process (4) SOCl2,Pd/BaSO4/H2

       PhCOOH+ClSOClPhCO+OSO+Cl + HCl          PhC(A)-O Cl + SO2 +HCl   PhCOCl PdBaSO4H2PhCOH 

Here, only in these two reactions acetic acid can be converted into acetaldehyde.

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