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Q.

Consider the following reaction,

A+2BP

Rate equation is given as d[B]dt=K[A] is valid for all concentrations of A & B. Equal volumes of 0.4 M A and 1.2 M B solutions are mixed. If K=6.93×104 sec1, correct statement(s) is/are 

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a

Time taken for B to become its concentration half is 1000 sec

b

Rate of reaction at 2000 sec is 6.93×105molL1sec1

c

Time taken for concentration of P to become 0.4 M is 6×103 seconds

d

Rate of product formation exponentially increases with time

answer is B, D.

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Detailed Solution

[A]=0.2M[B]=0.6M, KA=2×6.93×104sec, ty2=500sec.

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