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Q.

Consider the following reaction and identify the correct statement(s) for the balanced equation?
Au+Aqua    regia  X(aq)+Y+H2O [Given that: ‘Y’ is a diatomic molecule] 

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a

‘X’ is diamagnetic and ‘Y’ is paramagnetic

b

‘Y’ is paramagnetic with two unpaired electrons

c

1 mole Au reduces 3 moles of NO3

d

Aqua regia is a mixture of 1 part Conc.HNO3 and 3 parts Conc. HCl by volume.

answer is A, D.

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Detailed Solution

i) Au+4H++NO3+4Cl  AuCl4+NO+2H2O  
ii) X=[AuCl4],Y=NO  
iii) NO is paramagnetic with one unpaired electron 

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