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Q.

Consider the following reaction at 1000° C :

(a)  Zn(s)+12O2(g)ZnO(s);ΔG=360kJmolmol1

(b) C(s)+12O2(g)CO(g);ΔG=460kJmol1

Choose the correct statement at 1000° C.

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a

Choose the correct statement at 1000° C.

b

Zinc oxide can be reduced by C

c

Both statement (a) and (b) are true

d

Both statement (a) and (b) are false

answer is B.

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Detailed Solution

Zinc oxide can be reduced by C.

ZnO+CZn+CO

 ΔGRxn=460+360<0(spontaneous)

The formation of CO is more thermodynamically favourable at 1000° C, as may be observed from reactions.
So at this temperature, C can be reduced in zinc oxide.

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