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Q.

Consider the following reaction at 1000°C

1) Zn(s)+12O2( g)ZnO(s);ΔG0=-360 kJ mol-1

2) C(s)+12O2( g)CO(g);ΔG0=-460 kJ mol-1

Choose the correct statement

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a

Zinc can be reduced by C

b

Zinc oxide can be reduced by C

c

Zinc can be oxidised by CO

d

Zinc can be reduced by CO

answer is B.

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Detailed Solution

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Formation of CO is more thermodynamically favored at 1000°C.

The zinc oxide can be reduced by C at this temperature.

In Ellingham diagram, the ΔfG of C lies below that of ZnO. If the reduction is carried out at very high temperatures, the C will act as a reductant and can reduce ZnO.

ZnO(s)→ Zn(s)+12O2(g) ΔfGo=−360

C(s)+12O2(g)→ CO(s) ΔfGo=−460
Net reaction
ZnO(s)+ C(s)→ Zn(s)+ CO ΔfGo=−100 

As ΔfGo=−100kJ/mol , the reaction is spontaneous.

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