Q.

Consider the following reaction for which the change in enthalpy is positive.

2 A( g)+B(g)C(g)+D(g)

Which of the following will not affect the equilibrium?

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a

Presence of catalyst

b

Change in concentration of reactants 

c

Change in pressure 

d

Change in temperature

answer is D.

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Detailed Solution

2Ag + Bg   Cg + Dg ;H = +veΔn  =  23= 1

    Increase in pressure favours forward reaction
    the reaction is endothermic, forward reaction is favoured at high temperature.
Addition of A (or) B and removal of C (or) D favours forward reaction
Catalyst has no influence on equilibrium state. It increases both rate of forward reaction and rate of backward reaction to the same extent.

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