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Q.

Consider the following reaction for which the change in enthalpy is positive.

2 A( g)+B(g)C(g)+D(g)

Which of the following will not affect the equilibrium?

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a

Presence of catalyst

b

Change in concentration of reactants 

c

Change in pressure 

d

Change in temperature

answer is D.

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Detailed Solution

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Δng=1
Change in concentration of reactants Increase in concentration of reactants favours forward reaction and decrease in concentration of reactants favors backward reaction.
Change in pressure
Decrease / increase in pressure favors equilibrium in that direction where number of moles increases / decreases.
Change in temperature
Exothermic reaction - favours for low temperature.
Endothermic - favours for high temperature.
Catalyst alters rate of forward and backward reactions to same extent. Thus, it does not alter the equilibrium position.

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