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Q.

Consider the following reaction:

N2O42NO2(g);ΔHo=58KJ

For each of the following cases (a, b), the direction in which the equilibrium shifts is : 

(a)Temperature is decreased
(b)pressure is increased by adding N2 at constant T.

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a

(a)towards reactant, (b) no change 

b

(a)towards product,  (b) no change

c

(a) towards product, (b) towards reactant

d

(a) towards reactant, (b) towards product

answer is A.

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Detailed Solution

detailed_solution_thumbnail

According to Le-chatelier’s principle,
(i) For endothermic reaction, decrease in temperature, 
Equilibrium shift in the reactant side.
(ii) By adding inert gas at same temperature, on increase in 
Pressure, no shifting occurs.

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