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Q.

Consider the following reaction:
 N2O4(g)2NO2(g);ΔH0=+58kJ
For each of the following cases (a,b), the direction in which the equilibrium shifts is.
a) Temperature is decreased
b) Pressure is increased by adding N2  at constant  p.
 

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a

(a) towards product, (b) towards reactant

b

(a) towards reactant, (b) towards product

c

(a) towards reactant, (b) no change     

d

(a) towards product, (b) no change

answer is B.

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Detailed Solution

Increase in temperature favour forward reaction i.e. endothermic, Decreaese in temperature favour backward reaction 
Adding increases  N2 not participating in given reaction shifts the equilibrium towards more number of moles side at constant pressure.
 

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