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Q.

Consider the following reactions :
(i) PCl3 + 3H2 H3PO3 + 3HCl (ii) SF4 + 3H2 H3SO3 + 4HF
(iii) BCl3 + 3H2 H3BO3 + 3HCl (iv) XeF6 + 3H2 XeO3 + 6HF
Then according to given information the incorrect statement is :

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a

During the (iv) reaction the hybridisation of l8th group element does not change

b

During the (ii) reaction the hybridisation of 16th group element has been changed

c

During the (i) reaction the hybridisation of 15th group element does not change

d

During the (iii) reaction the hybridisation of 13th group element does not change

answer is D.

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Detailed Solution

PCl3sp3,H3PO3sp3SF4sp3d,H2SO3sp3BCl3sp2,H3BO3sp2XeF6sp3d2,XeO3sp3

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Consider the following reactions :(i) PCl3 + 3H20 → H3PO3 + 3HCl (ii) SF4 + 3H2O → H3SO3 + 4HF(iii) BCl3 + 3H2O → H3BO3 + 3HCl (iv) XeF6 + 3H2O → XeO3 + 6HFThen according to given information the incorrect statement is :