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Q.

Consider the following reactions:
i)  Glucose +ROHdryHCl  AcetalCH3CO2Ox. eq.of acetyl derivative acetyl derivative
ii)  Glucose Ni/H2ACH3CO2Oy.eq.of acetyl derivative 
iii)  Glucose  z.eq.of CH3CO2O acetyl derivative 
‘x’, ‘y’ and ‘z’ in these reactions are respectively.

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a

5, 4 & 5

b

4, 5 & 5

c

5, 6 & 5

d

4, 6 & 5

answer is B.

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Detailed Solution

i) Cyclic structure of glucose react with 4 equivalence of acetic anhydride
ii) Glucose reduces to sorbitol. Sorbitol react with 6 equivalence of acetic anhydride
iii) Linear structure of glucose react with 5 equivalence of acetic anhydride

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