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Q.

Consider the following reactions:
(i) PCl3+3H2OH3PO3+3HCl
(ii) SF4+3H2OH2SO3+4HF
(iii) BCl3+3H2OH3BO3+3HCl
(iv) XeF6+3H2OXeO3+6HF
Then according to given information the incorrect statement is:

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a

During the (iv) reaction the hybridization of 18th group element does not change

b

During the (iii) reaction the hybridization of 13th group element does not change

c

During the (ii) reaction the hybridization of 16th group element has been changed

d

During the (i) reaction the hybridization of 15th group element does not change

answer is A.

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Detailed Solution

 (i) PCl3sp3,H3PO3sp3  (ii) SF4sp3d,H2SO3sp3  (iii) BCl3sp2,H3BO3sp2  (iv) XeF6sp3d2,XeO3sp3
Reaction (iv) is incorrect

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Consider the following reactions:(i) PCl3+3H2O⟶H3PO3+3HCl(ii) SF4+3H2O⟶H2SO3+4HF(iii) BCl3+3H2O⟶H3BO3+3HCl(iv) XeF6+3H2O⟶XeO3+6HFThen according to given information the incorrect statement is: