Q.

Consider the following reactions,
(P) PH3+HIPH4+I-
(Q) NH3+HINH4+I-
(R) BF3+LiFLi4BF4-
Select the correct options :

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a

Reaction (P) involves maximum increase in bond angle.

b

In Q,HNH in NH3 less than that in NH4+

c

In P,HPH in PH3 is less than that in PH4+

d

Reactions (P),(Q) and (R) involve increase in bond angle.

answer is A, B, C.

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Detailed Solution

The bond angles of the compounds are,BF4=PH4+=NH4+=10928PH3=92;NH3=107;BF3=120

In (III), bond angle decreases.

Thus, option A, B and C are correct.

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