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Q.

Consider the following reaction,

Zn+2H+Zn2++H2

Half-life period is independent of concentration of Zn at constant pH. At constant Zn concentration, half-life is 10 minutes at pH = 2 and half-life is 100 minutes at pH = 3. Hence, rate law is :

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a

k[Zn]0H+2

b

k[Zn]H+2

c

k[Zn]H+

d

k[Zn]0H+

answer is A.

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Detailed Solution

r1=k1[Zn]; k1=k×102a; t1/2=10min=ln 2k1

r2=k2[Zn]; k2=k×109a; t1/2=100min=ln 2k2

 10100=k2k1=103102aa=1

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