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Q.

Consider the following redox reaction:
5I+IO3+6H+3I2+3H2O 
0.1 M solution of KI reacts with excess of  H2SO4 and  KIO3 solutions, according to above redox reaction.
Which of the following statements is INCORRECT?

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a

Equivalent weight of KIO3 is equal to  (Molecular  weight5)

b

100 mL of the KI solution reacts with 0.006 mole of  H2SO4

c

0.5 L of the KI solution produced 0.005 mole of  I2

d

200 mL of the KI solution react with 0.004 mole  KIO3

answer is C.

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Detailed Solution

Valance factor of  IO3- ion is 5

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Consider the following redox reaction:5I−+IO3−+6H+→3I2+3H2O 0.1 M solution of KI reacts with excess of  H2SO4 and  KIO3 solutions, according to above redox reaction.Which of the following statements is INCORRECT?