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Q.

Consider the following sequence of reactions:

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Which of the following statements is/are true for the compounds X, Y and Z ?

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a

In all three compounds, the chromium is in +6 oxidation state.

b

Z is a deep blue-violet compound which can be extracted in to ether but decomposes rapidly in aqueous solution into Cr3+ and dioxygen.

c

Y oxidizes aqueous KI solution to KIO3 in presence of dilute sulphuric acid.

d

Z contains two oxygen – oxygen bonds

answer is A, B, D.

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Detailed Solution

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Dichromate oxidizes iodide to iodine and not to iodate.

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