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Q.

Consider the following six conditions. (Serial number 1 to 6 ). Select those conditions which represent criteria for spontaneity. Answer the system to be closed.[Report your answer by adding the serial number of selected conditions. For example if serial number 1 and 2 satisfy then answer would be 0003.]

Serial Numbersconditions
1(dG)P,T>0
2(ΔS)universe >0
3(dU)S,V>0
4(dH)S,P<0
5(dS)UV<0
6(dS)H,P>0

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answer is 12.

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Detailed Solution

Criteria for spontaneously is:

(dG)P,T<0;(dS)univ >0;(dU)S,V<0;(dH)S,P<0

(dS)U,V>0;(dS)H,P>0

So, option 2,4 and 6 are correct
2 + 4 + 6 = 12

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