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Q.

Consider the following spontaneous reaction
 2C8H18(g)+25O2(g)16CO2(g)+18H2O(g)  The sign of ΔH,ΔS,ΔG would be respectively 

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a

,,-

b

,+,

c

+,+,

d

+,,+

answer is B.

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Detailed Solution

2C8H18(g)+25O2(g)16CO2(g)+18H2O(g)
The given reaction is a combustion reaction. Hence 
this will be an exothermic reaction.
 i.e. ΔH=ve  Further Δn=(18+16)-(2+25)=+ ve   i.e. ΔS=+ ve  ΔG=ΔHTΔS=ΔHTΔS=ve

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