Q.

Consider the following standard reduction potentials. Fe3+(aq)+eFe2+(aq),E0=0.77VH2O2(aq)+2e2OH(aq),E0=0.88V. For the voltaic cell reaction below, calculate the Fe2+ concentration (in M) that would be needed to produce a cell potential equal to 0.16V at 25°C when  OH=0.1M,Fe3+=0.5M and 
H2O2=0.35M;)2Fe2+(aq)+H2O2(aq)2Fe3+(aq)+2OH(aq

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a

0.6M

b

0.3M

c

0.41M

d

0.35M

answer is D.

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Detailed Solution

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ECell 0=0.11VE=E0+0.05912logFe+22H2O21Fe+32×OH20.16=0.11+0.05912logFe+22×(0.35)1(0.5)2×1012Fe+2=0.354

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