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Q.

Consider the following statement.
I. When O2 is converted into O22+ bond order decreases.
II. O2 molecule is paramagnetic because it contains two unpaired electrons in π*2px and π*2py molecular orbitals.
III. The bond length in NO is greater than NO+.
Choose the correct option.

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a

I and II

b

II and III

c

Only I

d

II and IV

answer is C.

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Detailed Solution

Statement II and III are correct.

The molecular orbital configuration of O2  molecule is as follows:
   σ   1s2,   σ   *1s2  σ   2s2   σ   *2s2  σ   2p2z,π2px2    =π2py2      ,π*2px1=π*2py1
There are 10 bonding and 6 nonbonding electrons in the orbitals according to the molecular orbital configuration.

Therefore,  Bond order =12[Bonding-antibonding]
12[106]=12(4)=2
Thus, the bond order O2 is 2.

 The molecular orbital configuration of O2+2 is 
σ1s2,σ*1s2,σ2s2,σ*2s2,σ2pz2,π2px2=π2py2
There are 10 bonding  and 4 nonbonding electrons in the orbitals according to the molecular orbital configuration.
Therefore, Bond order =12[Bonding-antibonding]
=12[104]=3.

Hence statement I is incorrect.

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