Q.

Consider the following statements : 
a. Electron density in xy Plane in  3dx2y2 Orbital is zero 
b. In H-like species, the energy of orbitals depends only on the ‘n’ value.
c. 2𝑠 orbital has only one spherical node 
d. For 2pz orbital yz Is the nodal plane. 
The correct statements are 

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a

a and c

b

b and c

c

Only b

d

a, b, c, d

answer is A.

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Detailed Solution

Number of  spherical Nodes = (n1)
Number of  Nodal planes =
In  3dx2y2 orbital 4 lobes along the x and y axes & hence e¯  density available on x & y axes 
Order of energy of orbitals in H-like species is as follows
1s < 2s = 2p < 3s = 3p = 3d

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