Q.

Consider the following statements and arrange in the order of true / false :

S1 : In SnCl2, the bonding takes place in ground state and the bond angle ClSnCl is slightly less than 120°.

S2 : The molecular geometry of XeF7+ is pentagonal bipyramidal having two different XeF bond lengths.

S3 : In SF4, the bond angles, instead of being 9" 0 and 180° are 89° and 177° respectively due the presence of a lone pair.

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a

TFT

b

TTT

c

TTF

d

FTT

answer is A.

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Detailed Solution

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S2:XeF7+ is pentagonal bipyramidal having axial and equatorial bonds of different lengths.

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