Q.

Consider the following statements and arrange in the order of true/false as given in the codes 

S1: Concentrated solution of an alkali metal in liquid ammonia is diamagnetic
S2:  Increasing stability of the peroxide and super oxide of alkaline earth metal down the group, is due to the stabilization of large anions by large cations through lattice energy effects.
S3:  In the vapour phase  BeCl2 tends to form a chloro –bridged dimer.
S4:  Beryllium hydroxide can reacts with acid and alkali

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a

F F F F

b

T F T F

c

F T F T

d

T T T T

answer is A.

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Detailed Solution

S1:  In concentrated solution unpaired electrons pair up together and become diamagnetic 
S2:  and  S3: are correct statements.
S4: B(OH)2+2OH-[Be(OH)4]2-    beryl late ion 
B(OH)2+2HCl +2H2O[Be(OH2)4]Cl2

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