Q.

Consider the following statements and select the correct set of codes using T (True) and F (False) in the given sequence.

(p) PI5(s) does not exist due to steric crowding.

(Q) All possible angles in BF2Cl are 120

(R) In NSiH33 lone pair of N is present in sp3 hybrid orbital.

(S) d-orbital used in hybridization of P in PBr5(s) is dz2

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a

TFTT

b

FFFF

c

FTTT

d

TFTF

answer is C.

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Detailed Solution

Due to the size of iodine, which is quite enormous, five iodine atoms cannot fit around the P atom to form phosphorus pentaiodide.

All possible angle in BF2Cl is not equal to120 degree.

Since Si possesses empty d-orbitals, N(SiH3)3 has a planar structure because the lone pair N-atom is moved to the silicon's empty d-orbitals (pπdπ overlap).

All the options are false.

Hence, the option C is correct.

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