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Q.

Consider the following statements :
S1: The percentage of s-character in the orbital forming S-S bonds and P-P bonds in S8 and P4 molecule respectively are not same.
S2: In SF4the bond angles, instead of being 90 and 180 are 89and respectively due to the repulsion between lone pair and bond pair of electrons,

S3 : Aqueous H3PO4 is syrupy (i.e. more viscous than water).
S4:SiO2 crystal may be considered as giant molecule in which eight-membered rings are formed with alternate silicon and oxygen atoms of these.

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a

S1 and S2 are correct only

b

S2S3 and S4 are correct only

c

All statements above are correct

d

S1S2 and Sa are correct only

answer is C.

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Detailed Solution

S1: The percentage of s-character in the orbital forming S-S bonds and P-P bonds in S8 and P4 molecule respectively are not same.
S2: In SF4the bond angles, instead of being 90 and 180 are 89and respectively due to the repulsion between lone pair and bond pair of electrons,

S3H3PO4 has very strong H-bonding.

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Correct option is C.

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