Q.

Consider the following statements : 

Statement-1: Cu2+ ions are reduced to Cu+ by potassium iodide and potassium cyanide both, when taken in excess. 

Statement-2: H2S will precipitate the sulphide of all the metals from the solutions of chlorides of Cu, Zn and Cd if the solution is aqueous. 

Statement-3: The presence of magnesium is confirmed in qualitative analysis by the formation of a white crystalline precipitate of MgNH4PO4 . 

Statement-4: Calomel on reaction with potassium iodide gives red precipitate.

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a

TTTF 

b

TTTT 

c

TTFF

d

TFTF

answer is B.

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Detailed Solution

Hg2Cl2KIHg2I2                   (Green ppt.)

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