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Q.

Consider the following statements : 

Statement-I: The Co(ox)33 complex is diamagnetic and gains stability through chelation. 

Statement-2: The CoNO264 is an inner orbital complex involving d2sp3 hybridizations and is paramagnetic. 

Statement-3: The complex PtCl42 is square planar and diamagnetic. and arrange in the order of true/false :

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a

TFT

b

TTT

c

TTF

d

FFT

answer is A.

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Detailed Solution

Since Co(ox)33 is a chelating ligand, exhibits d2sp3 hydrolyzation, and is diamagnetic they are more stable.

NO2 is a more potent ligand, and its d7 configuration results in one of the 3d-electron leaps to higher energy orbitals, which gives it the d2sp3 hybridization and complex paramagnetic property.

Pt(II) has a 5d8 configuration with a higher CFSE, according to  CFSE[PtCl4]2

Hence, the correct option is Ạ

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Consider the following statements : Statement-I: The Co(ox)33− complex is diamagnetic and gains stability through chelation. Statement-2: The CoNO264 is an inner orbital complex involving d2sp3 hybridizations and is paramagnetic. Statement-3: The complex PtCl42− is square planar and diamagnetic. and arrange in the order of true/false :