Banner 0
Banner 1
Banner 2
Banner 3
Banner 4
Banner 5
Banner 6
Banner 7
Banner 8

Q.

Consider the following statements : 

Statement-I: The Co(ox)33 complex is diamagnetic and gains stability through chelation. 

Statement-2: The CoNO264 is an inner orbital complex involving d2sp3 hybridizations and is paramagnetic. 

Statement-3: The complex PtCl42 is square planar and diamagnetic. and arrange in the order of true/false :

see full answer

High-Paying Jobs That Even AI Can’t Replace — Through JEE/NEET

🎯 Hear from the experts why preparing for JEE/NEET today sets you up for future-proof, high-income careers tomorrow.
An Intiative by Sri Chaitanya

a

TFT

b

TTT

c

TTF

d

FFT

answer is A.

(Unlock A.I Detailed Solution for FREE)

Best Courses for You

JEE

JEE

NEET

NEET

Foundation JEE

Foundation JEE

Foundation NEET

Foundation NEET

CBSE

CBSE

Detailed Solution

Since Co(ox)33 is a chelating ligand, exhibits d2sp3 hydrolyzation, and is diamagnetic they are more stable.

NO2 is a more potent ligand, and its d7 configuration results in one of the 3d-electron leaps to higher energy orbitals, which gives it the d2sp3 hybridization and complex paramagnetic property.

Pt(II) has a 5d8 configuration with a higher CFSE, according to  CFSE[PtCl4]2

Hence, the correct option is Ạ

Watch 3-min video & get full concept clarity

Ready to Test Your Skills?

Check your Performance Today with our Free Mock Test used by Toppers!

Take Free Test

score_test_img

Get Expert Academic Guidance – Connect with a Counselor Today!

whats app icon