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Q.

Consider the following statements :

Statement-I: MnCl63,FeF63 andCoF63are paramagnetic having four, five, and four unpaired electrons respectively.

Statement-2: Valence bond theory gives a quantitative interpretation of the thermodynamic stabilities of coordination compounds.

Statement-3: The crystal field splitting Δ0, , depends upon the field produced by the ligand and charge on the metal ion. 

and arrange in the order of true/false.

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a

TTT

b

TFT

c

FTF

d

TFF

answer is B.

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Detailed Solution

Since VBT explains magnetic data and provides a quantitative explanation. Third, VBT does not differentiate between weak and strong field ligands.

Only statement B is incorrect while others are correct.

Hence, the correct option is B.

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