Q.

Consider the following statements 
1.The basic strength of hydroxides of lanthanides decreases from La(OH)3 to Lu(OH)3
2.The lanthanoid ions Lu3+Yb2+ and Ce4+ are diamagnetic

3.the correct order of ionic radii of Ce3+,La3+Pm3+ and Yb3+ is Yb3+<Pm3+<La3+<Ce3+ Which of the statements given above is/are correct?

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a

1,2 only

b

1 only

c

1, 2 and 3

d

None of these

answer is B.

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Detailed Solution

Lu=[Xe]4f145d16s2; Yb=[Xe]4f145d06s2 Ce=[Xe]4f15d16s2

Basic strength decreases from La(OH)3​ to Lu(OH)4​

Hence, (1) is incorrect. 

The given Ions contain no unpaired electrons and therefore, are diamagnetic. 

Hence, (2) is correct.

Atomic and ionic radii of Lanthanides decrease from La to Lu.

Their order of ionic radii:  Yb+3<Pm+3<Ce+3<La+3. Hence, (3) is incorrect.

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