Q.

Consider the following statements.
I. In general, the temperature dependence of the equilibrium constant depends on the sign of H for the reaction.
II. The equilibrium constant for an exothermic reaction (negative, H)decreases as the temperature increases.
III. The equilibrium constant for an endothermic reaction (positive,H)increases as the temperature increases.
IV. Temperature changes affect the equilibrium constant and rates of reactions.
Choose the correct statements.

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a

I and II

b

I, II, III and IV

c

III and IV

d

I, II and III

answer is D.

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Detailed Solution

(i) In general, the temperature dependence of the equilibrium constant depends on the sign of H for the reaction.
(ii) The equilibrium constant for an exothermic reaction (negative H) decreases as the temperature increases.
(iii) The equilibrium constant for an endothermic reaction (positive H) increases as the temperature increases.
(iv) Temperature changes affect the equilibrium constant and rates of reaction.

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