Q.

Consider the following statements:

(P) MnH2O4SO4 is paramagnetic.

(Q) Crystal field splitting energy (i.e. Δ0 ), in CrH2O63+ is higher than in CrH2O62+.

(R) Wilkinson catalyst RhClPh3P3, a red-violet complex is diamagnetic and square planar.

(S) HgCo(SCN)43, a deep blue complex is paramagnetic and tetrahedral.

and of these select the correct set from the given options.

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a

 P, R and S only

b

P, Q, R and S

c

P and S only 

d

Q, R and S only

answer is D.

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Detailed Solution

The correct statements are,
P) [Mn(H2O)4]SO4 is paramagnetic.
Q) Crystal field splitting energy (i,e. Δ0 ), in CrH2O63+ is higher than in CrH2O62+.
R) Wilkinson catalyst RhClPh3P3, a red-violet complex is diamagnetic and square planar. 
S) HgCoSCN4, a deep blue complex is paramagnetic and tetrahedral.

Thus, the correct option is D.

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