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Q.

Consider the following statements: 

Statement-I: CrNH363+ is an inner orbital complex with crystal field stabilization energy equal to 1.2Δ0

Statement-2: The complex formed by joining the CN- ligands to Fe3+ ion has theoretical value of 'spin only' magnetic moment equal to 1. 73 BM

Statement-3 Na2S+Na2Fe(CN)5NONa4 Fe(CN)5 NOS In reactant and product the oxidation states of iron are same 

and arrange in the order of true/false.

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a

FFF

b

TTF

c

TTT

d

FTF

answer is B.

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Detailed Solution

Since number of unpaired electrons obtained by joining the  CN- ligand to  Fe3+ due to which its magnetic  moment is 1.73 BM.

Since CrNH363+ exist in the t2g orbital and having oxidation state 3 is an inner orbital complex with  crystal field stabilization energy equal to 1.2Δ0 

Since the value of Fe in reactant is +3 and product is +2 option C is incorrect.
Oxidation state in reactant

x+5(1)+0=2x=+3

Oxidation state of Fe in product (y)

y+5(1)+1(1)=4y=+2

Hence the correct option is B.

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