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Q.

Consider the following system. 
Three different aqueous solutions each having initial volume 100 ml are taken and kept in contact at constant temperature as shown in figure below:

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After sufficient time (Consider 100% dissociation of strong electrolytes)

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a

Volume of both KCl and AlCl3 solutions will increase

b

Final volume of  AlCl3 solution will be 4003ml

c

Decrease in volume of urea solution with respect to initial solution is  1003ml

d

There will be no change in volume of KCl solution.  

answer is A, B, C.

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Detailed Solution

Ans. (A,B,C) 
After sufficient time osmotic pressure of all solution will become same. As T is same molar concentration should be same, for this ratio of volume should be the same as that of moles ratio. 
Urea                 : KCl                : AlCl 
20 m moles     30 m moles      40 m moles 
Total volume (300 ml) should be divided in  
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