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Q.

Consider the following two 1st order reaction :

AP......(1)

BQ......(2)

Reaction (i) is 75 % complete in 4 hrs while reaction (ii) takes 16 hr for 75% completion under identical conditions. By how many hours, half life of (ii) reaction is greater than the half life of (i)?

 

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answer is 6.

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Detailed Solution

In the first reaction, half life,

t1/2=2 hr 

Half life for second reaction

t1/2=8 hr 

The difference between the half life,

=8-6 =2 hrs
 

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Consider the following two 1st order reaction :A→P......(1)B→Q......(2)Reaction (i) is 75 % complete in 4 hrs while reaction (ii) takes 16 hr for 75% completion under identical conditions. By how many hours, half life of (ii) reaction is greater than the half life of (i)?