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Q.

Consider the Galvanic cell
 Ag|AgNO3(0.001M)||AgNO3(0.1M)|Ag,EAg+,Ag0=0.80  volt
Choose the CORRECT options when both half cells are connected by an electronic conductor.
 

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a

Entropy of universe increases

b

Current flows from right electrode to left electrode in external circuit.

c

Standard electrode potential of the cell decreases with time.

d

Standard electrode potential of the cell increases with time.

answer is A, B.

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Detailed Solution

 Ecell=E2E1
{EAg+,Ag0+0.0591nlog[Ag+]right}{EAg+Ag0+0.0591nlog[Ag+]left}
+0.0591nlog[Ag+]right0.0591nlog[Ag+]left
0.0591nlog{[Ag+]right[Ag+]left} = 0.05911log0.10.001=0.0591  log100
0.05911log0.10.001=0.0591  log100  = 0.1182 volt
Since Ecell   is positive, the right electrode will act as cathode (where reduction occurs) and the left electron will act as anode (where oxidation occurs). The electrons will thus travel from left to right in external circuit.
 

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