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Q.

Consider the galvanic cell, Pt(s)|H2(1bar)|HCl(aq)(1M)|Cl2(g)(1bar)|Pt(s) After running cell for some time, the concentration of the electrlolyte is automatically raised to 3 M HCl. Molar conductivity of the 3M HCl is about 240 S cm2mol1 and limiting molar conductivity of HCl is about 420 S cm2mol1. If Kb of water is 0.52 K kg/mol, what is the boiling point of the electrolyte at the end of the experiment?

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a

375.6 K

b

377.8 K

c

378.1 K

d

380.3 K

answer is A.

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Detailed Solution

For strong electrolytes, Debye-Huckel -onsager equation is followed

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