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Q.

Consider the given reaction.

Mg3B2HCl(aq)[X]+MgCl2

Choose the incorrect choice regarding [X] and [Y].

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a

[X] with air and [Y] on strong heating (red heat) give the same compound.

b

[X] is BCl3 and [Y] is H3BO3.

c

[X]+H2OHCl (aq)[Y]+H2

d

In [Y], boron completes its octet by removing H+ from water molecule.

answer is B.

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Detailed Solution

Reaction of Mg3B2 with HCl is:

2Mg3B2+12HCl2B2H6X+6MgCl2

Above reaction indicates that X is B2H6. Reaction of X (B2H6) with water is:

B2H6+3H2OH3BO3(Y)+3H2

Above reaction indicates that Y is H3BO3.

Reaction of X with air and heating of Y gives the same compound, boric oxide (B2O3).

B2H6+3O2B2O+3H2O2H3BO3B2O3+3H2O

H3BO3 is electron deficient and complete its octet by removal of proton from water molecule.

B(OH)3+2HOHB(OH)4-+H3O+

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