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Q.

Consider the heterogeneous equilibrium in a closed container

NH4HS(s)    NH3(g)  +   H2S(g)

If more NH4HS is added to the equilibrium

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a

No effect on partial pressure of NH3 and H2S

b

Partial pressure of H2S

c

Partial pressure of NH3 increases

d

Total pressure in the container increases

answer is D.

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Detailed Solution

NH4HS(s)    NH3(g)  +   H2S(g)

KP=NH3(g)  ×  H2S(g)

Partial pressures of NH3 and H2O do not affect NH4HS(s) because NH4HS(s) is solid for solid active mass unity.

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