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Q.

Consider the hydrated ions of Ti2+, V2+, Ti3+ and Sc3+. The correct order of their spin-only magnetic moments is

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a

Ti3+<Ti2<Sc3+<v2+

b

V2+<Ti2+<Ti3+<Sc3+

c

Sc3+<Ti3+<Ti2+<V2+

d

Sc3+<Ti3+<V2+<Ti2+

answer is C.

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Detailed Solution

μ=n(n+2)BM

Were, n = no. of unpaired electrons.

and BM = Bohr magneton

The electronic configurations of a given transition metal ion are listed.

Sc3+(Z=21)1s22s22p63s23p63d04s0

Ti3+(Z=22)1 s22 s22p63 s23p63 d14 s0

Ti2+(Z=22)1 s22s22p63 s23p63 d24S0

V2+(Z=23)1s22s22p63s23p63d34s0

X = Atomic number.

Because the magnetic moment is proportional to the number of unpaired electrons.

Sc3+3d0

n=0μ=0(0+2)=0BM

Ti3+3d1

n=1μ=1(1+2)=1×3=3Bm

Ti2+3d2

n=2⇒μ=2(2+2)=2×4=8BM

V2+3d3

n=3μ=3(3+2)=3×5=15Bm

Because they have 0, 1, 2, and 3 unpaired electrons, the correct increasing order of magnetic moment is Sc3+<Ti3+<Ti2+<V2+

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